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Jairo A. Gómez-Cuaspud https://orcid.org/0000-0002-9645-516X

Ariatna Y Neira-Guio https://orcid.org/0000-0001-5519-4939

Enrique Vera-López https://orcid.org/0000-0003-4150-9308

Luís C. Canaría-Camargo https://orcid.org/0000-0001-5460-238X

Abstract

Lithium cobalt oxide (LiCoO2) is one of the most relevant components in lithium-ion batteries. The array of sought-after features of LiCoO2 depends on its synthesis method. In this work we synthesized and characterized a nanocrystalline LiCoO2 oxide obtained with a wet chemistry synthesis method. The oxide obtained was a homogeneous powder in the nanometric range (5-8 nm) and exhibited a series of improved properties. Characterization by FTIR and UV-Vis techniques led to identifying citrate species as main products in the first step of the synthesis process. X-ray diffraction (XRD), Raman, and transmission electron microscopy (TEM) characterizations led to identifying a pure crystalline phase of the synthesized LiCoO2 oxide. Steady state electrical characterization and solid-state impedance spectroscopy determined the high conductance of the synthesized oxide. All these features are desirable in the design of cathodes for lithium ion batteries.

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Keywords

Nanomaterial, Li-Ion Batteries, nanocrystalline, steady-state

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How to Cite
Gómez-Cuaspud, J., Neira-Guio, A., Vera-López, E., & Canaría-Camargo, L. (2020). Chemical synthesis and steady state characterization of a nanocrystalline lithium cobalt oxide. Universitas Scientiarum, 25(2), 203-225. https://doi.org/10.11144/Javeriana.SC25-2.csas
Section
Ciencia de los Materiales / Material Science / Ciência dos Materiais
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