Selective extraction and modification of cellulose from sugar cane bagasse (Saccharum officinarum)
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Sep 1, 2022
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Abstract
This paper’s aim was the synthesis of a flocculant useful in the production of panela as an alternative to replace polyacrylamide and improve food safety in Boyacá, a Colombian district. The cellulose was extracted by using a treatment with potassium hydroxide and followed by acid hydrolysis. From the extracted cellulose, cationic dialdehyde cellulose (CDAC) was synthesized and both cellulose and CDAC were characterized using infrared spectroscopy, FTIR, thermogravimetric analysis (TGA), differential thermal analysis (DSC) Scanning Electron Microscopy (SEM) and RAMAN. The cellulose extracted by hydrolysis from sugarcane bagasse with bleaching, gave yield of 50 % and crystallinity index of 77 %. Its modification to aldehyde is 95 % reliable at a temperature of 65 oC and 2 h; with higher temperature and time the performance is affected. The dialdehyde process allows a modification to be carried out and to be more easily attacked at carbons 2 and 3, leaving cationized cellulose for later use as a flocculant in the panela production process as a traditional solution of flocculants and polyacrylamide. Extraction, modification, and tests for the clarification of the panela juice were carried out in triplicate.
Keywords
sugarcane, flocculant, polyacrylamide, cellulose
References
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doi: 10.1016/j.reffit.2016.11.015
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doi: 10.1016/j.aca.2005.07.005
[2] Fao L. Mejorando la producción de panela en Colombia. Revista de Agroecología. 1: 1–6, 2017
[3] García EY, Salgado GS, Bolio LG, Córdova SS Lagunes LC, Falcon CR, Veleva L. Métodos para extraer celulosa de la paja de caña de azúcar (Saccharum spp.). Agro productividad. 10(11): 54–59, 2017.
[4] López-Martínez A, et al. Obtención de celulosa a partir de bagazo de caña de azúcar (Saccharum Officinarum L.): Aislamiento y caracterización. Agro productividad. 9(7): 1–12, 2016.
[5] Zumalacárregui, et al. Potencialidades del bagazo para la obtención de etanol frente a la generación de electricidad. Revista ingeniería investigacion tecnologia. 16(3): 407–418, 2015.
[6] Kaushal I, Saharan P, Kumar V, Sharma A, Umar A. Superb sono-adsorption and energy storage potential of multifunctional Ag-Biochar composite. Journal of Alloys and Compounds. 785: 240–249, 2019.
doi: 10.1016/j.jallcom.2019.01.064
[7] Wang S, Lu A, and Zhang L. Recent advances in regenerated cellulose materials. Progress in Polymer Science. 53: 169–206, 2016.
doi: 10.1016/j.progpolymsci.2015.07.003
[8] Poletto M, Pistor V, and Zattera AJ. Structural Characteristics and Thermal Properties of Native Cellulose. Cellulose - Fundamental Aspects. 2013.
doi: 10.5772/50452
[9] Khatri Z, Mayakrishnan G, Hirata Y, Wei K, Kim I, Cationic-cellulose nanofibers: Preparation and dyeability with anionic reactive dyes for apparel application. Carbohydrate Polymers. 91(1): 434–443, 2013.
doi: 10.1016/j.carbpol.2012.08.046
[10] Sirvio J, Hyvakko U, Liimatainen H, Niinimaki J, Hormi O. Periodate oxidation of cellulose at elevated temperatures using metal salts as cellulose activators. Carbohydrate Polymers. 83(3): 1293–1297, 2011.
doi: 10.1016/j.carbpol.2010.09.036
[11] Tejado A, Alam MN, Antal M, Yang H, van de Ven TGM. Energy requirements for the disintegration of cellulose fibers into cellulose nano fibers. Cellulose. 19(3): 831–842, 2012.
[12] Sirviö J, Honka A, Liimatainen H, Niinimäki J, Hormi O. Synthesis of highly cationic water-soluble cellulose derivative and its potential as novel biopolymeric flocculation agent. Elsevier. 86: 266–270, 2011.
doi: 10.1016/j.carbpol.2011.04.046
[13] Lengowski EC, Ines G, de Muniz B. Avaliação de métodos de obtenção de celulose com diferentes graus de cristalinida de Cellulose acquirement evaluation methods with different degrees of crystallinity. Scientia Forestalis. 185–194, 2013.
[14] Tibolla H, Pelissari FM, Menegalli FC. Cellulose nanofibers produced from banana peel by chemical and enzymatic treatment. LWT - Food Science and Technology. 59(2): 1311–1318, 2014.
doi: 10.1016/j.lwt.2014.04.011
[15] Matsuzawa Y, Ayabe M, Nishino J, Kubota N, Motegi M. Evaluation of char fuel ratio in municipal pyrolysis waste. In Fuel. 83(11–12): 1675–1687, 2004.
doi: 10.1016/j.fuel.2004.02.006
[16] Ciolacu D, Ciolacu F, Popa VI. Amorphous cellulose – structure and characterization. Cellulose chemistry and technology. 45: 13–21, 2011.
[17] Morán VP, Vazquez J. Extracción de celulosa y obtención de nano celulosa a partir de fibra sisal – caracterización. SAM asociación Argentina de materiales. 1: 16–17, 2008.
[18] Matsuzawa Y, Ayabe M, Nishino J, Kubota N, Motegi M. Evaluation of char fuel ratio in municipal pyrolysis waste. Fuel. 83(11–12): 1675–1687, 2004
doi: 10.1016/j.fuel.2004.02.006
[19] Moreno L, Medina O, Rojas AL. Mucilage and cellulosic derivatives as clarifiers for the improvement of the non-centrifugal sugar production process. Food Chemistry. 367, 2021.
doi: 10.1016/j.foodchem.2021.130657
[20] Prieto F, Jiménez E, Acevedo OA, Rodríguez R, Canales R A, Prieto J. Obtaining and Optimization of Cellulose Pulp from Leaves of Agave tequilana Weber Var. Blue. Preparation of Hand made Craft Paper. Waste and Biomass Valorization. 0(0): 1–17, 2018.
doi: 10.1007/s12649-018-0262-5
[21] Du L, Wang J, Zhang Y, Qi C, Wolcott MP, Yu Z. A co-production of sugars, ligno sulfonates, cellulose, and cellulose nanocrystals from ball-milled woods. Bioresource Technology. 238: 254–262, 2017.
doi: 10.1016/j.biortech.2017.03.097
[22] Sirviö J, Honka A, Liimatainen H, Niinimäki J, Hormi O. Synthesis of highly cationic water-soluble cellulose derivative and its potential as novel biopolymeric flocculation agent. Elsevier. 86: 266–270, 2011.
doi: 10.1016/j.carbpol.2011.04.046
[23] Nechyporchuk O, Belgacem MN, Bras J. Production of cellulose nanofibrils: A review of recent advances. Elsevier. 93: 2–25, 2016.
doi: 10.1016/j.indcrop.2016.02.016ç
[24] Kono H. Cationic flocculants derived from native cellulose: Preparation, biodegradability, and removal of dyes in aqueous solution. Resource Technology. 3(1): 55–63, 2017.
doi: 10.1016/j.reffit.2016.11.015
[25] Zhang Y, Jiao J, Ren Y, Wu X, Zhang Y. Determination of acrylamide in infant cereal-based foods by isotope dilution liquid chromatography coupled with electrospray ionization tandem mass spectrometry. Analytica Chimica Acta. 551(1): 150–158, 2005.
doi: 10.1016/j.aca.2005.07.005
How to Cite
Rincón Fuentes, L. M., Moreno Bastidas, L. M., & Medina Vargas, O. J. . (2022). Selective extraction and modification of cellulose from sugar cane bagasse (Saccharum officinarum). Universitas Scientiarum, 27(3), 254–272. https://doi.org/10.11144/Javeriana.SC273.seam
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Section
Food Chemistry
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